By W. Eberhardt (auth.), Professor Dr. Wolfgang Eberhardt (eds.)
Applications of synchrotron radiation in physics, chemistry, fabrics technology, and biology has now matured from an unique experimental box right into a well-established sector of technological know-how. The spectroscopy of molecules and molecular adsorbates on surfaces is one zone of technology, the place, some time past, synchrotron-radiation-related reviews had made an effect on knowing the ground-state homes in addition to the dynamics. With the hot high-brightness synchrotron-radiation resources forward, it will definitely stay a box of very energetic examine. This quasi-monograph stories the present country of the sector for either, the energetic study scientist, and the hot graduate scholar wishing to turn into accustomed to this box of research.
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Additional resources for Applications of Synchrotron Radiation: High-Resolution Studies of Molecules and Molecular Adsorbates on Surfaces
Kuhlenbeck 52 Fig. 34. 7 F f' 7i. 8 0 >- 01 L. 1 11. B --D F-R -direction (cf Fig. 36b:2) _ F-R-direction (ct. Fig. 361),) oR-point (ct. Fig. 36 1),) eA-point (cf Fig. 36 b;» Fig. 35. 1 C 6H 6/Os(OOOI) 0 photoelectron spectra of the 2a 1g level as a function of angle, and in Fig. 35 the dispersions are plotted for two photon energies along the direction indicated in the inset. The two p~ssible domains of the overlayer are indicated. There exists a common direction r ~ A in both domains along which the experiments have 2.
11) refer to the bands after hybridization has been taken into account, while the dotted lines refer to the non-hybridized bands. We start the discussion by first considering the band dispersion neglecting hybridization. Clearly, the dispersion of the nonhybridized 5O'-bands should be similar to the 4O'-dispersion. In fact, this is our result. The splittings calculated for various symmetry points, however, differ considerably. This is expected since the spatial extent of the 50' molecular orbitals is different from the 40' molecular orbitals.
These states transform according to the bi and b2 representations if C 2v point group symmetry is assumed. They exhibit opposite intensity variations if the plane oflight incidence is changed from  to . The b i state shows strong emission in the  plane and weak emission in the [1 TO] plane, while the b2 is weak along  and strong along [1 TO], respectively. 25 depicts that the b 2 orbital has a node along the C-C while the bi orbitals has a node perpendicular to the C-C-axis.